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The biosynthesis of lobeline in intact Lobelia inflata plants was studied. The piperidine nucleus is derived from lysine by way of a symmetrical intermediate. Both C6–C2 units are derived from phenylalanine. Acetate is shown not to be involved in the biosynthesis.
M. F. Keogh and D. G. O'Donovan, J. Chem. Soc. C, 1970, 2470 DOI: 10.1039/J39700002470
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