The presence of 17β-groups (methoxy-, acetoxy-, ethyl, or 1,5-dimethylhexyl) or of unsaturation in ring D had little effect upon the position of equilibrium between substituted 5α- and 5β-androstan-6-ones.
D. N. Jones and R. Grayshan, J. Chem. Soc. C, 1970, 2421 DOI: 10.1039/J39700002421
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