D-Homo-5α-androstan-17a-one, -17-one, and -16-one, and the corresponding epimeric pairs of alcohols and acetates have been prepared. These are valuable reference compounds quasi-enantiomeric to derivatives monosubstituted in ring A. N.m.r. data are considered; o.r.d. and c.d. curves have been treated elsewhere.
D. N. Kirk, W. Klyne, C. M. Peach and M. A. Wilson, J. Chem. Soc. C, 1970, 1454 DOI: 10.1039/J39700001454
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