2,6-Difluoroaniline and several related primary amines are oxidised by peroxybenzoic acid in chloroform to the corresponding nitroso-compounds. Treatment of 2,6-difluoroaniline with sodium azide gives 4-fluoro-2,1,3-benzoxadiazole, which on nitration gives the 7-nitro-derivative.
L. Di Nunno, S. Florio and P. E. Todesco, J. Chem. Soc. C, 1970, 1433 DOI: 10.1039/J39700001433
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