Dehydrogenation with mercuric acetate in the lupane series. Part III. A revised structure for dehydrolupeol derivatives
Abstract
The new double bond introduced into lupeol, betulin diacetate, and methyl acetylbetulinate by dehydrogenation with mercuric acetate is shown to be in conjugation with the side-chain double bond. Two previously unidentified saturated acetates arising from the oxidation of dihydrodehydrolupenyl acetate (VIIa) are now identified.