Issue 4, 1970

Elimination of nitriles in retro-diene reactions

Abstract

The Diels–Alder reactions of the oxazoles (II; R = H or Me) and (III) with diphenylcyclopropenone and acetylenic dienophiles have been studied. In no case were the bicyclic adducts isolable, but ready elision of hydrogen cyanide or a nitrile occurred, giving a γ-pyrone (V) and furans as the major heterocyclic products.

Article information

Article type
Paper

J. Chem. Soc. C, 1970, 552-556

Elimination of nitriles in retro-diene reactions

R. Grigg and J. L. Jackson, J. Chem. Soc. C, 1970, 552 DOI: 10.1039/J39700000552

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