Issue 0, 1970

Nitrogen inversion in tetrahydro-1,2-oxazines and the stereochemistry of geneserine

Abstract

The temperature variation of the n.m.r. spectrum of geneserine is explained in terms of a nitrogen-inversion process in the 1,2-oxazine ring. It is argued that the process is compatible with a cis rather than a trans ring fusion.

Article information

Article type
Paper

J. Chem. Soc. B, 1970, 1739-1741

Nitrogen inversion in tetrahydro-1,2-oxazines and the stereochemistry of geneserine

F. G. Riddell, D. A. R. Williams, C. Hootelé and N. Reid, J. Chem. Soc. B, 1970, 1739 DOI: 10.1039/J29700001739

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