From optical measurements of solutions containing fluoranil (2,3,5,6-tetrafluorobenzoquinone) and hexamethylbenzene in 1,2-dichloroethane over a range of temperature, ΔH⊖=–3·9 ± 0·2 kcal mol–1 and ΔS⊖=–10 ± 1 cal mol–1 K–1 for complex formation, have been obtained. These values are in good agreement with those obtained from n.m.r. chemical-shift measurements.
R. Foster and I. B. C. Matheson, J. Chem. Soc. B, 1970, 1713 DOI: 10.1039/J29700001713
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