The thermodynamic functions of ionisation of dimethylcyanoacetic and isopropylcyanoacetic acids from 5 to 45 °C have been determined by an improved conductance method. The data for four cyanoacetic acids are compared in relation to the influence of alkyl substitution and the operation of the compensation law.
D. J. G. Ives and P. G. N. Moseley, J. Chem. Soc. B, 1970, 1655 DOI: 10.1039/J29700001655
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