The n.m.r. spectra of ortho-substituted nitrosobenzenes have been measured and the chemical shifts of o-aromatic, o-methyl, o-methoxyl, and o-t-butyl protons have been found to be anomalous. These anomalous chemical shifts are explained mainly in terms of the large magnetic anisotropy of the nitroso-group.
R. Okazaki and N. Inamoto, J. Chem. Soc. B, 1970, 1583 DOI: 10.1039/J29700001583
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