The mechanism of the reduction of 2-methylamino-3,5-dinitropyridine is elucidated by carrying out the reaction with sodium boro-hydride and -deuteride in water and deuterium oxide as solvents. The tautomeric structure and stereochemistry of the tetrahydro-reduction product is discussed with reference to the n.m.r. spectra.
E. Bordignon, A. Signor, I. J. Fletcher, A. R. Katritzky and J. R. Lea, J. Chem. Soc. B, 1970, 1567 DOI: 10.1039/J29700001567
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