Issue 0, 1970

The mechanism of acyl sulphonate reactions. Part I. Solvolysis of o-sulphobenzoic anhydride in hydroxylic solvents

Abstract

Rate constants have been determined for the hydrolysis and deuteriolysis of o-sulphobenzoic anhydride in 90% dioxan and for the solvolyses in five alcohols containing either 6·67% dioxan or ether. The hydrolysis is subject to negative salt effects. The results are discussed in terms of solvent properties.

Article information

Article type
Paper

J. Chem. Soc. B, 1970, 388-390

The mechanism of acyl sulphonate reactions. Part I. Solvolysis of o-sulphobenzoic anhydride in hydroxylic solvents

R. M. Laird and M. J. Spence, J. Chem. Soc. B, 1970, 388 DOI: 10.1039/J29700000388

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