Direct evidence has been obtained for the formation of N-acetylimidazole in imidazole-catalysed hydrolysis of aryl acetates with both good and poor leaving groups. No evidence could be found for bifunctional catalysis in the hydrolysis of p-tolyl acetate catalysed by imidazol-4-ylacetate ion.
D. G. Oakenfull, J. Chem. Soc. B, 1970, 197 DOI: 10.1039/J29700000197
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