The electric dipole moments of some 1,3,5-trialkylhexahydro-1,3,5-triazines have been measured in cyclohexane solutions and interpreted in terms of their conformations. The tri-t-butyl compound exists to about 85% in the conformation with one of the t-butyl groups axial; this is the first example of an unconstrained t-butyl group preferring the axial position.
R. A. Y. Jones, A. R. Katritzky and M. Snarey, J. Chem. Soc. B, 1970, 135 DOI: 10.1039/J29700000135
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