Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Electric discharge reactions of silane and germane with some volatile group VI species

J. E. Drake  and  C. Riddle  

Abstract

The action of a silent electric discharge on equimolar mixtures of the following hydrides: SiH4/H2S, SiH4/H2Se, GeH4/H2S, GeH4/H2Se, SiH4/GeH4/H2S, SiH4/GeH4/H2Se, SiH4/MeSH, and GeH4/MeSH, has been investigated. Analysis of the reaction products by 1H n.m.r. and mass spectroscopy indicates the formation of the previously known mixed and ternary hydrides: SiH3SH, (SiH3)2S, SiH3SeH, (SiH3)2Se, GeH3SH, (GeH3)2S, GeH3SeH, (GeH3)2Se, MeSSiH3, and MeSGeH3. The new compounds SiH3SGeH3 and SiH3SeGeH3 are obtained from discharges of the ternary mixtures.

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Article information

DOI
https://doi.org/10.1039/J19700003134
Article type
Paper

J. Chem. Soc. A, 1970, 3134-3136

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Electric discharge reactions of silane and germane with some volatile group VI species

J. E. Drake and C. Riddle, J. Chem. Soc. A, 1970, 3134 DOI: 10.1039/J19700003134

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