Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Superoxide-bridged binuclear complexes of rhodium(III)

A. W. Addison  and  R. D. Gillard  

Abstract

The preparations are described of the blue or purple complex compounds of formulae [ClL4Rh·O2·RhL4Cl]Y3 where L = pyridine or γ-picoline and Y = an anion, and [(H2O)L4Rh·O2·RhL4(H2O)]Y5. The presence of the superoxide bridge is demonstrated by magnetic, spectroscopic, and analytical data. Acid-base equilibria for the aquo-complexes are mentioned. An account is given of the reduction forming the peroxo-bridged dimer [ClL4Rh·O2·RhL4Cl]Y2.

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Article information

DOI
https://doi.org/10.1039/J19700002523
Article type
Paper

J. Chem. Soc. A, 1970, 2523-2526

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Superoxide-bridged binuclear complexes of rhodium(III)

A. W. Addison and R. D. Gillard, J. Chem. Soc. A, 1970, 2523 DOI: 10.1039/J19700002523

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