The formal potential of the Pd(s),Pd2+(aq) couple in 3·94m-HClO4 has been determined at 5° intervals from 10 to 40 °C. From the data the entropy of Pd2+(aq) relative to S(H+,aq)= 0 is calculated to be 25 ± 6 cal. deg.–1 mole–1 at 25 °C. The entropy value of Pd2+(aq) is estimated to be 7 ± 10 cal. deg.–1 mole–1 at zero ionic strength and 25 °C.
R. M. Izatt, D. J. Eatough, C. E. Morgan and J. J. Christensen, J. Chem. Soc. A, 1970, 2514 DOI: 10.1039/J19700002514
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