Peroxodisulphate oxidation of Fe(LL)2(CN)2, where LL = 2,2′-bipyridyl, 1,10-phenanthroline, or one of its substituted derivatives, follows second-order kinetics. Rate constants correlate with electron-withdrawing or -releasing properties of the ligand substituents.
J. Burgess, J. Chem. Soc. A, 1970, 2114 DOI: 10.1039/J19700002114
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