The relative energies of the d orbitals of transition-metal ions in eight-co-ordinate complexes with D2d symmetry have been calculated using a point-charge model. These energies have been shown to be sensitive to the detailed geometry assumed and also to the crystal-field parameters Dq and Cp.
C. D. Garner and F. E. Mabbs, J. Chem. Soc. A, 1970, 1711 DOI: 10.1039/J19700001711
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