The 57Co(electron capture)57Fe process taking place in 57Co-doped crystals of K3FeIII(C2O4)3,3H2O and K3FeIII(C2O4)3 produces some divalent 57FeII. The reduced species may be Fe(C2O4)22–, which has previously been observed in γ-irradiated potassium trisoxalatoferrate(III).
J. Fenger, K. E. Siekierska and A. G. Maddock, J. Chem. Soc. A, 1970, 1456 DOI: 10.1039/J19700001456
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