γ-Radiolysis of frozen trimethyl phosphate at 77°K, gave methyl and H2COP(O)(OMe)2 radicals. The methyl radical was lost at ca. 120°K, and the e.s.r. spectrum of the more stable radical at this temperature was characteristic of a system in which the α-hydrogen atoms were rapidly reorienting.
A. Begum, S. Subramanian and M. C. R. Symons, J. Chem. Soc. A, 1970, 1334 DOI: 10.1039/J19700001334
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