A qualitative survey is presented of the enhancement or reversal of 13C resonances in electron–nuclear double-resonance experiments. 13C Resonances in natural abundance have been observed for 47 compounds, and their enhancement or reversal are interpreted in terms of variation caused by structural effects of the scalar coupling with the radical electron.
T. C. Cannon, R. E. Richards and D. Taylor, J. Chem. Soc. A, 1970, 1180 DOI: 10.1039/J19700001180
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