The mass spectra of beryllium dialkyls R2Be (R = Me, Et, Prn, Pri, Bui, or But) have been examined and all ions identified. At low source temperature most of these compounds produce ions derived from electron-deficient associated species. Ionization potentials lead to bond dissociation energies in the molecular ion D(RBe+–R) of about 45 kcal. mole–1.
D. B. Chambers, G. E. Coates and F. Glockling, J. Chem. Soc. A, 1970, 741 DOI: 10.1039/J19700000741
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