The protonation of some polynuclear carbonyl complexes in concentrated sulphuric acid has been studied and the new complexes [HRu3(CO)12]PF6 and [HOs3(CO)12]PF6 have been isolated. The kinetic isotope effect observed in these protonation reactions has been investigated and the new complex HOsCo3(CO)12 has been prepared.
J. Knight and M. J. Mays, J. Chem. Soc. A, 1970, 711 DOI: 10.1039/J19700000711
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