The single-crystal polarised electronic spectrum of the pseudotetrahedral complex dichlorobis(triphenylphosphine)nickel(II) is reported. The spectrum is partially assigned in C2v symmetry, assuming an electric-dipole mechanism and suggests a splitting of the parent 3T1(F) and 3T2(F) manifolds by 4·8 and 7·8 kk respectively.
R. J. Fereday, B. J. Hathaway and R. J. Dudley, J. Chem. Soc. A, 1970, 571 DOI: 10.1039/J19700000571
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