Benzaldimines, ArCH = NR (R = But or PhCO2), on treatment with di-isopropyl peroxydicarbonate in warm benzene, generates benzimidoyl radicals, ArĊ= NR, which subsequently decompose to give benzonitrile together with the radical R.
H. Ohta and K. Tokumaru, J. Chem. Soc. D, 1970, 1601a DOI: 10.1039/C2970001601A
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