2H-Hexafluoropropyl azide reacts with a number of low-valent metal complexes to form a series of mononuclear fluoroalkylimido-derivatives: some of these complexes undergo ligand-addition reactions.
M. J. McGlinchey and F. G. A. Stone, J. Chem. Soc. D, 1970, 1265a DOI: 10.1039/C2970001265A
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