The sodium salts of the tosylhydrazones of o-alkenyl aryl ketones decompose thermally with retention of nitrogen to give 2,3-benzodiazepines, rather than by a carbenic route.
J. T. Sharp and P. B. Thorogood, J. Chem. Soc. D, 1970, 1197b DOI: 10.1039/C2970001197B
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