Paramagnetic species have been detected in γ-irradiated silver perchlorate–cycloalkene complexes at room temperature and identified as Ag+ cycloalkenyl radical, with spin density on Ag ranging from 4·6% to 1·5% and in a decreasing order with increasing size of the alkene rings.
D. R. Gee and J. K. S. Wan, J. Chem. Soc. D, 1970, 641b DOI: 10.1039/C2970000641B
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