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Synthetic methods are reported for four new thiohalides, MoSCl3, WSCl3, and WSX4(X = Cl, Br), whose physical properties indicate polymeric structures for the MSCl3 compounds (with M–S–M bridging bonds), but the presence of terminal W = S bonds for WSX4.
D. Britnell, G. W. A. Fowles and R. Mandyczewsky, J. Chem. Soc. D, 1970, 608a DOI: 10.1039/C2970000608A
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