SCHEDULED MAINTENANCE
Kinetic and product analysis studies of the alkaline hydrolysis of hexakis(aryloxy)cyclotriphosphazenes in 25 vol.% aqueous diglyme revealed an SN2-type mechanism for cleavage of the first aryloxy-side-group from phosphorus: the hydrolysis rate was considerably enhanced by 2- or 4-nitro-groups and retarded by 4-methyl groups in the aryl ring.
H. R. Allcock and E. J. Walsh, J. Chem. Soc. D, 1970, 580a DOI: 10.1039/C2970000580A
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