The dissociation of [Rh(Ph3P)3Cl] to Ph3P and [Rh(Ph3P)2Cl] occurs quite readily in benzene but is completely inhibited by the presence of even small amounts of alcohol.
R. L. Augustine and J. F. Van Peppen, J. Chem. Soc. D, 1970, 497a DOI: 10.1039/C2970000497A
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