A new type of SN2′ reaction in which the nucleophile enters trans to the leaving group occurs in the acylolysis of a 4β-halogeno-5β-chloestan-3-one to give a 2β-acyloxy-5β-chloestan-3-one as a product.
J. Y. Satoh and T. T. Takahashi, J. Chem. Soc. D, 1970, 1714 DOI: 10.1039/C29700001714
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