Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system

A. J. Carty; D. P. Madden; M. Mathew; Gus J. Palenik; T. Birchall

doi:10.1039/C29700001664

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Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system

A. J. Carty, D. P. Madden, M. Mathew, Gus J. Palenik and T. Birchall

Abstract

Reaction of Fe₂(CO)₉ with 3,5,7-triphenyl-4H-1,2-diazepine leads to cleavage of the N–N bond and formation of a nitrogen bridged complex which has been shown by X-ray crystallography to be a bicyclo[5,1,1]derivative.

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DOI: https://doi.org/10.1039/C29700001664
Article type: Paper

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J. Chem. Soc. D, 1970, 1664-1665

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Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system

A. J. Carty, D. P. Madden, M. Mathew, G. J. Palenik and T. Birchall, J. Chem. Soc. D, 1970, 1664 DOI: 10.1039/C29700001664

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Journal of the Chemical Society D: Chemical Communications

Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system

Abstract

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Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system

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