Issue 23, 1970

Label scrambling in the hydrolysis and borohydride trapping products of [1,1-2H2]cyclopropylmethyl, [1-2H1]cyclobutyl, and [2,2,4,4-2h4]cyclobutyl methanesulphonates

Abstract

Cyclopropylmethyl and cyclobutyl methanesulphonates appear to solvolyse by forming in the ratdetermining step two and one intimate ion pairs, respectively, which then further ionize to the corresponding equilibrating solvent-separated ion pairs.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1636-1637

Label scrambling in the hydrolysis and borohydride trapping products of [1,1-2H2]cyclopropylmethyl, [1-2H1]cyclobutyl, and [2,2,4,4-2h4]cyclobutyl methanesulphonates

Z. Majerski, S. Borčbić and D. E. Sunko, J. Chem. Soc. D, 1970, 1636 DOI: 10.1039/C29700001636

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