Label scrambling in the hydrolysis and borohydride trapping products of [1,1-2H2]cyclopropylmethyl, [1-2H1]cyclobutyl, and [2,2,4,4-2h4]cyclobutyl methanesulphonates
Abstract
Cyclopropylmethyl and cyclobutyl methanesulphonates appear to solvolyse by forming in the ratdetermining step two and one intimate ion pairs, respectively, which then further ionize to the corresponding equilibrating solvent-separated ion pairs.
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