Thermal rearrangements of dimethylvinylidenebenzobicyclo[n,1,0]alkenes (n= 3,4) appear to proceed via concerted processes involving hydrogen atom migration from a carbon atom α to the cyclopropane ring to one of the carbon atoms comprising the allene skeleton.
I. H. Sadler and J. A. G. Stewart, J. Chem. Soc. D, 1970, 1588 DOI: 10.1039/C29700001588
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