Direct evidence has been obtained for the intermediate formation of cyclobutenes in the thermal cis–trans-isomerization of simple conjugated dienes, and kinetic data suggests that this is the major reaction pathway for the isomerization.
H. M. Frey, A. M. Lamont and R. Walsh, J. Chem. Soc. D, 1970, 1583 DOI: 10.1039/C29700001583
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