The n.m.r. spectra of the N-carbodithioic acid sodium salts of piperidines having equatorial α-alkyl substituents indicate that conformational inversion of the piperidine ring occurs upon formation of these derivatives.
T. P. Forrest and S. Ray, J. Chem. Soc. D, 1970, 1537 DOI: 10.1039/C29700001537
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