Issue 22, 1970

Germanium complexes of ruthenium and osmium dodecacarbonyls: metal–metal heterocycles: crystal structure of [Me2GeRu(CO)3]3

Abstract

Pyrolysis of the compounds (Me3Ge)2M′(CO)4[M′= Ru or Os] affords polynuclear complexes [Me2GeM′(CO)3]3 shown to contain heterocyclic rings of six metal atoms, and the anion [Me3GeRu(CO)4] reacts with various metal halides to give inter alia pentanuclear [Me3GeRu(CO)4]2Hg.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1477-1478

Germanium complexes of ruthenium and osmium dodecacarbonyls: metal–metal heterocycles: crystal structure of [Me2GeRu(CO)3]3

J. Howard, S. A. R. Knox, F. G. A. Stone and P. Woodward, J. Chem. Soc. D, 1970, 1477 DOI: 10.1039/C29700001477

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