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Two new free-radical reactions involving rearrangement of α-hydroxy-alkoxy-radicals and fragmentation of β-hydroxy-alkylperoxy-radicals have been inferred from the study of the influence of various hydroxylic organic solutes on the radiation-chemically induced oxidation of FeSO4 and on the oxidation of FeSO4 by H2O2.
D. Bunn and R. C. Das, J. Chem. Soc. D, 1970, 1456 DOI: 10.1039/C29700001456
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