Issue 21, 1970

Conformational interchange in acyclic sulphonamides: evidence for directional pπdπ bonding in N–S bonds

Abstract

The low temperature n.m.r. spectra of dialkylsulphamoyl chlorides indicate a considerable barrier (ca. 11·5 kcal mol–1) to rotation around the N–S bond; the ground-state conformation is similar to that predicted for an α-sulphonyl carbanion.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1418-1419

Conformational interchange in acyclic sulphonamides: evidence for directional pπdπ bonding in N–S bonds

W. B. Jennings and R. Spratt, J. Chem. Soc. D, 1970, 1418 DOI: 10.1039/C29700001418

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