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Barriers to syn–anti-isomerism via torsion about the C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
N double bond and via inversion at iminonitrogen obtained using CNDO/2 calculations indicate that the lowering of the barrier by heteroatoms attached to the imino-carbon atom is a reflection of a torsional contribution of the mechanism.
M. Raban, J. Chem. Soc. D, 1970, 1415 DOI: 10.1039/C29700001415
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