SCHEDULED MAINTENANCE
Barriers to pseudorotation in AsV species, in which a five-membered ring is constrained to span the equatorial positions in the trigonal bipyramidal intermediates, are in the range of 20–23 kcal mol–1, and thus are comparable with the corresponding barriers in PV systems with similar structures.
J. P. Casey and K. Mislow, J. Chem. Soc. D, 1970, 1410 DOI: 10.1039/C29700001410
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