Intramolecular participation by carboxylate anion in the solvolysis of the hindered ester 2-carboxyphenyl mesitoate in anhydrous methanol, occurs entirely by a nucleophilic mechanism in contrast to aspirin which previously has been shown to involve the kinetically equivalent general base mechanism.
H. D. Burrows and R. M. Topping, J. Chem. Soc. D, 1970, 1389 DOI: 10.1039/C29700001389
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