Issue 20, 1970

Do radical and ionic pathways of decomposition of arenediazonium ions in acidic methanol proceed via a common intermediate?

Abstract

In acidic methanol, arenediazonium ions de-compose either by a radical mechanism, forming ArH, or by an ionic mechanism to form ArOMe; in some cases the former pathway predominates under N2 and the latter under O2, but the rates are sufficiently similar to suggest that perhaps both proceed via a common intermediate.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1363-1364

Do radical and ionic pathways of decomposition of arenediazonium ions in acidic methanol proceed via a common intermediate?

T. J. Broxton, J. F. Bunnett and C. H. Paik, J. Chem. Soc. D, 1970, 1363 DOI: 10.1039/C29700001363

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