In the protonation of acetylene–platinum(0) complexes of type Pt(ac)(PPh3)2 to give alkenylplatinum(II) complexes, trans-PtX(alkenyl)(PPh3)2, the platinum and the added proton are mutually cis on the alkenyl double bond.
B. E. Mann, B. L. Shaw and N. I. Tucker, J. Chem. Soc. D, 1970, 1333 DOI: 10.1039/C29700001333
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