Reaction of 2-(alkoxyamino)diaryl sulphones with sodium alkoxides at 20° results in loss of alkoxy-groups and furnishes diphenylamine derivatives and quinone di-imines; trapping experiments and comparison with reactions designed to generate o-(phenylsulphonyl)-aryl nitrenes indicate that a nitrene mechanism is unlikely.
M. F. Grundon, R. H. Hall, R. McD. Hunter and D. J. Maitland, J. Chem. Soc. D, 1970, 1280 DOI: 10.1039/C29700001280
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