Histamine replaces serinate which is co-ordinated to CuIIvia dissociative (replacement of serine by H2O) and associative (second order) paths; under the reaction conditions employed the protonated form of histamine is the attacking species.
V. S. Sharma and D. L. Leussing, J. Chem. Soc. D, 1970, 1278 DOI: 10.1039/C29700001278
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