The photolysis of adamantanone oxime (I) in acetic acid under a nitrogen stream at room temperature for 6 hr yields 4-azatricyclo[4,3,1,1]undecan-5-one (III) and adamantanone (II) in 89 and 8% yields, respectively, without any fragmentation product.
T. Sasaki, S. Eguchi and T. Toru, J. Chem. Soc. D, 1970, 1239 DOI: 10.1039/C29700001239
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