The crystal structure of trans-bromo-(5-methoxynortricycl-3-enyl)dipyridinepalladium has been determined from three-dimensional single crystal X-ray data: this compound provides an example of internal insertion of an olefinic bond into a metal–carbon σ-bond.
E. Forsellini, G. Bombieri, B. Crociani and T. Boschi, J. Chem. Soc. D, 1970, 1203 DOI: 10.1039/C29700001203
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